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Modeling of solids segregation in circulating fluidized bed boilers

Xuan YAO, Tao WANG, Jia ZHAO, Hairui YANG, Hai ZHANG

《能源前沿（英文）》 2011年第5卷第1期页码 115-119 doi: 10.1007/s11708-010-0103-0

摘要： Segregation always occurs in a circulating fluidized bed (CFB) because of the wide distribution of particle size and density of the bed material. Terminal velocity has a significant influence on solids segregation; thus, it is convenient to describe the segregation tendency using single particle terminal velocity . This paper proposes a segregation model in CFB boilers based on the Cell Model. In each cell along the riser, varied-sized particles have different tendencies toward segregation; finer particles are carried out more easily, while coarser ones tend to sink into the cell. It is assumed that the average terminal velocity , corresponding to the mean particle size in the cell, has a segregation index of = 1.0 as the reference point. The segregation index of particles with higher terminal velocity is lower than 1.0, while that for finer particles is larger than 1.0. The empirical formulae of segregation parameters, namely and , are derived by optimizing experimental data in published literature. The test result of ash size distribution in a 220 t/h CFB boiler validates the reasonableness of the model.

关键词： segregation model terminal velocity circulating fluidized bed (CFB)

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Performance evaluation of circulating fluidized bed incineration of municipal solid waste by multivariate

Hua Tao, Pinjing He, Yi Zhang, Wenjie Sun

《环境科学与工程前沿（英文）》 2017年第11卷第6期 doi: 10.1007/s11783-017-0945-3

摘要： This first nationwide survey was conducted to evaluate the overall performance of the circulating fluidized bed (CFB) incineration of municipal solid waste (MSW) in 2014-2015 in China. Total 23 CFB incineration power plants were evaluated. The data for monthly average flue gas emission of particles, CO, NO , SO and HCl were collected over 12 consecutive months. The data were analyzed to assess the overall performance of CFB incineration by applying the Mahalanobis distance as a multivariate outlier detection method. Although the flue gas emission parameters had met the Chinese national emission standards, there were 11 total outliers (abnormal behavior) detected in 6 out of 23 CFB incineration power plants from the perspective of the MSW incineration performance. The results demonstrate that it is more important for a better performance of CFBs to reduce the frequencies of the MSW load changes, rather than the magnitudes of the MSW load changes, particularly reducing the frequencies in the range of 10% and more of the load changes, under the same and stable conditions. Furthermore, the overloading occurs more often than the underloading during the operation of the CFB incineration power plants in China. The frequent overloading is 0% to 30% of the designed capacity. To achieve the stable performance of CFBs in practice, an appropriately designed MSW storage capacity is suggested to build in a plant to buffer and reduce the frequency of the load changes.

关键词： Municipal solid waste Incineration Circulating fluidized bed Load change Multivariate outlier detection

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Development of a supercritical and an ultra-supercritical circulating fluidized bed boiler

Junfu LYU, Hairui YANG, Wen LING, Li NIE, Guangxi YUE, Ruixin LI, Ying CHEN, Shilong WANG

《能源前沿（英文）》 2019年第13卷第1期页码 114-119 doi: 10.1007/s11708-017-0512-4

摘要： The supercritical circulating fluidized bed (CFB) boiler, which combines the advantages of CFB combustion with low cost emission control and supercritical steam cycle with high efficiency of coal energy, is believed to be the future of CFB combustion technology. It is also of greatest importance for low rank coal utilization in China. Different from the supercritical pulverized coal boiler that has been developed more than 50 years, the supercritical CFB boiler is still a new one which requires further investigation. Without any precedentor engineering reference, Chinese researchers have conducted fundamental research, development, design of the supercritical CFB boilers independently. The design theory and key technology for supercritical CFB boiler were proposed. Key components and novel structures were invented. The first 600 MWe supercritical CFB boiler and its auxiliaries were successfully developed and demonstrated in Baima Power Plant, Shenhua Group as well as the simulator, control technology, installation technology, commissioning technology, system integration and operation technology. Compared with the 460 MWe supercritical CFB in Poland, developed in the same period and the only other supercritical one of commercial running in the word beside Baima, the 600 MWe one in Baima has a better performance. Besides, supercritical CFB boilers of 350 MWe have been developed and widely commercialized in China. In this paper, the updated progress of 660 MWe ultra-supercritical CFB boilers under development is introduced.

关键词： supercritical circulating fluidized bed boiler development demonstration

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Flow boiling heat transfer in circulating fluidized bed

Xiaoguang REN , Jiangdong ZHENG , Sefiane KHELLIl , Arumemi-Ikhide MICHAEL ,

《能源前沿（英文）》 2009年第3卷第1期页码 85-89 doi: 10.1007/s11708-008-0067-5

摘要： In order to enhance heat transfer and mitigate contamination in the boiling processes, a new type of vapor-liquid-solid (3-phase) circulating fluidized bed boiling system has been designed, combining a circulating fluidized bed with boiling heat transfer. Experimental results show an enhancement of the boiling curve. Flow visualization studies concerning flow hydrodynamics within the riser column are also conducted whose results are presented and discussed.

关键词： vapor-liquid-solid three phase flow boiling heat transfer circulating fluidized bed

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Heat transfer in a large-scale circulating fluidized bed boiler

CHENG Leming, WANG Qinhui, SHI Zhenglun, LUO Zhongyang, NI Mingjiang, CEN Kefa

《能源前沿（英文）》 2007年第1卷第4期页码 477-482 doi: 10.1007/s11708-007-0071-5

摘要： Heat transfer of a furnace in a large-scale circulating fluidized bed (CFB) boiler was studied based on the analysis of available heat transfer coefficient data from typical industrial CFB boilers and measured data from a 12 MW

关键词： available coefficient industrial large-scale circulating analysis

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Development of a hydrodynamic model and the corresponding virtual software for dual-loop circulatingfluidized beds

Shanwei Hu, Xinhua Liu

《化学科学与工程前沿（英文）》 2021年第15卷第3期页码 579-590 doi: 10.1007/s11705-020-1953-6

摘要： Dual-loop circulating fluidized bed (CFB) reactors have been widely applied in industry because of their good heat and mass transfer characteristics and continuous handling ability. However, the design of such reactors is notoriously difficult owing to the poor understanding of the underlying mechanisms, meaning it has been heavily based on empiricism and stepwise experiments. Modeling the gas-solid CFB system requires a quantitative description of the multiscale heterogeneity in the sub-reactors and the strong coupling between them. This article proposed a general method for modeling multi-loop CFB systems by utilizing the energy minimization multiscale (EMMS) principle. A full-loop modeling scheme was implemented by using the EMMS model and/or its extension models to compute the hydrodynamic parameters of the sub-reactors, to achieve the mass conservation and pressure balance in each circulation loop. Based on the modularization strategy, corresponding interactive simulation software was further developed to facilitate the flexible creation and fast modeling of a customized multi-loop CFB reactor. This research can be expected to provide quantitative references for the design and scale-up of gas-solid CFB reactors and lay a solid foundation for the realization of virtual process engineering.

关键词： multi-loop circulating fluidized bed mathematical modeling energy minimization multiscale virtual fluidization mesoscale structure

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Circulating fluidized bed biological reactor for nutrients removal

CUI Yubo, LIU Hongbo, BAI Chunxue

《环境科学与工程前沿（英文）》 2008年第2卷第3期页码 349-353 doi: 10.1007/s11783-008-0051-7

摘要： A new biological nitrogen removal process, which is named herein “The circulating fluidized bed bioreactor (CFBBR)”, was developed for simultaneous removal of nitrogen and organic matter. This process was composed of an anaerobic bed (Riser), aerobic bed (Downer) and connecting device. Influent and nitrified liquid from the aerobic bed enters the anaerobic bed from the bottom of the anaerobic bed, completing the removal of nitrogen and organic matter. The system performance under the conditions of different inflow loadings and nitrified liquid recirculation rates ranging from 200% to 600% was examined. From a technical and economic point of view, the optimum nitrified liquid recirculation rate was 400%. With a shortest total retention time of 2.5 h (0.8 h in the anaerobic bed and 1.5 h in the aerobic bed) and a nitrified liquid recirculation rate of 400% based on the influent flow rate, the average removal efficiencies of total nitrogen (TN) and soluble chemical oxygen demand (SCOD) were found to be 88% and 95%, respectively. The average effluent concentrations of TN and SCOD were 3.5 mg/L and 16 mg/L, respectively. The volatile suspended solid (VSS) concentration, nitrification rate and denitrification rate in the system were less than 1.0 g/L, 0.026–0.1 g NH-N/g VSSd, and 0.016–0.074 g NO-N/g VSSd, respectively.

关键词： soluble chemical bioreactor biological nitrogen optimum nitrified nitrogen removal

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Development and technical progress in large-scale circulating fluidized bed boiler in China

Zhong HUANG, Lei DENG, Defu CHE

《能源前沿（英文）》 2020年第14卷第4期页码 699-714 doi: 10.1007/s11708-020-0666-3

摘要： Circulating fluidized bed (CFB) boilers has realized the clean and efficient utilization of inferior coal like gangue and coal slime, high sulfur coal, anthracite, petroleum coke, oil shale and other resources. As a country with the largest amount of CFB boilers and the largest installed capacity in the world, China has 440 100–600 MW CFB boilers with a total capacity of 82.29 GW , including 227 units of 135 MW , 95 units of 300 MW , and 24 supercritical units. The statistics of typical 100–300 MW CFB boilers showed that the average number of unplanned shut-down was only 0.37 times per year, among which the 135 MW was 0.26 times per year and 300 MW was 0.46 times per year. The auxiliary power ratio of some 300 MW CFB boilers based on flow-pattern reconstruction can be reduced to about 4%, which is closed to the same level of pulverized coal (PC) boilers. This paper summarizes the development process and application status of China’s large-scale CFB boilers, analyzes the characteristics and technical performance of the iconic units, and introduces solutions to the problems such as water wall wear and bottom ash cooling.

关键词： CFB boiler installed capacity reliability economics ultra-low emission China

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Heat flux distribution on circulating fluidized bed boiler water wall

LU Junfu, YUE Guangxi, YANG Hairui, ZHANG Jiansheng, YU Long, ZHANG Man, YANG Zhongming

《能源前沿（英文）》 2008年第2卷第2期页码 134-139 doi: 10.1007/s11708-008-0027-0

摘要： The future of circulating fluidized bed (CFB) combustion technology is in raising the steam parameters to supercritical levels. Understanding the heat flux distribution on the water wall is one of the most important issues in the design and operation of supercritical pressure CFB boilers. In the present paper, the finite element analysis (FEA) method is adopted to predict the heat transfer coefficient as well as the heat flux of the membrane wall and the results are validated by direct measurement of the temperature around the tube. Studies on the horizontal heat flux distribution were conducted in three CFB boilers with different furnace size, tube dimension and water temperature. The results are useful in supercritical pressure CFB boiler design.

关键词： horizontal different furnace temperature FEA measurement

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循环流化床燃烧低污染排放技术研究展望

柯希玮,蒋苓,吕俊复,岳光溪

《中国工程科学》 2021年第23卷第3期页码 120-128 doi: 10.15302/J-SSCAE-2021.03.009

摘要：

在污染物排放标准日趋严格、 2060 年前实现碳中和的背景下，深度挖掘循环流化床（CFB）燃烧技术的低污染排放潜力，进一步提高 CFB 锅炉的市场竞争力，对于煤炭清洁高效利用、能源转型升级具有重要意义。本文在阐述 CFB 燃烧污染物排放特性的基础上，分析了主流 CFB 锅炉低污染排放技术及应用，结合我国能源发展战略和相关政策，提出了 CFB 燃烧在污染物排放控制技术方面的发展建议。研究认为，需大力开发炉内原始低排放 CFB 燃烧技术，在保证锅炉效率的前提下，通过流态重构、燃烧组织来突破 CFB 锅炉污染物排放极限。着眼于煤炭能源长远发展，支持与超临界 / 超超临界，智能运行，碳捕集、利用与封存，储能等技术高度结合的新一代超低排放 CFB 燃烧技术研发；加快对现存中小容量 CFB 锅炉的优化升级；发挥 CFB 燃烧燃料适应性广的优势，推广生物质燃烧发电，促进对低热值燃料、城市垃圾、各工业废弃物的低成本高效清洁消纳；挖掘 CFB 锅炉的深度调峰能力并保持低污染排放性能，提高运行灵活性及对新能源的消纳能力；加强 CFB 燃烧脱硫灰渣的综合利用，关注 N2O 排放问题。还需从全局角度合理制定污染物排放标准和相关政策，引导包括 CFB 燃烧在内的能源行业健康发展。

关键词：煤炭清洁利用循环流化床污染控制碳中和燃料适应性新能源消纳

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Activity and characteristics of “Oxygen-enriched” highly reactive absorbent for simultaneous flue gas desulfurization and denitrification

Yi ZHAO,Tianxiang GUO,Zili ZANG

《环境科学与工程前沿（英文）》 2015年第9卷第2期页码 222-229 doi: 10.1007/s11783-014-0636-2

摘要： An “Oxygen-enriched” highly reactive absorbent was prepared by mixing fly ash, lime and a small quantity of KMnO for simultaneous desulfurization and denitrification. Removal of SO and NO simultaneously was carried out using this absorbent in a flue gas circulating fluidized bed (CFB). The highest simultaneous removal efficiency, 94.5% of SO and 64.2% of NO, was achieved under the optimal experiment conditions. Scanning Electron Microscope (SEM) and Accessory X-ray Energy Spectrometer (EDX) were used to observe the surface characteristics of fly ash, lime, “Oxygen-enriched” highly reactive absorbent and the spent absorbent. An ion chromatograph (IC) and chemical analysis methods were used to determine the contents of sulfate, sulfite, nitrate and nitrite in the spent absorbents, the results showed that sulfate and nitrite were the main products for desulfurization and denitrification respectively. The mechanism of removing SO and NO simultaneously was proposed based on the analysis results of SEM, EDX, IC and the chemical analysis methods.

关键词： “Oxygen-enriched” highly reactive absorbent Surface characteristics Flue gas circulating fluidized bed Simultaneous desulfurization and denitrification

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Suspended solid abatement in a conical fluidized bed flocculator

Dandan ZHOU, Shuangshi DONG, Keyu LI, Huizhong JIANG, Dandan SHANG

《环境科学与工程前沿（英文）》 2013年第7卷第1期页码 127-134 doi: 10.1007/s11783-012-0415-x

摘要： With the random movement of silica gel beads in a conical fluidized bed, micro-vortices resulting from the fluidization promoted the collision and aggregation of suspended fine kaolin powders. The abatement efficiencies of the suspended fine solids under several hydrodynamic conditions were studied, and a suitable control strategy for operating the conical fluidized bed flocculators was identified. The suspended solids abatement efficiency was found to increase with increasing Camp Number and flocculation time ( ), but decreased with the increase of velocity gradient ( ) within the range studied in this research (165.1–189.6 s ). The abatement efficiencies were all more than 60% at the range of = 165–180 s and = 15–33 s at an initial kaolin solid concentration of 150 mg·L , polymer aluminum chloride dosage of 60 mg·L and sedimentation time of 20 min. However, the formation of flocs was influenced by the liquid backmixing. Excessive backmixing caused the breakup of flocs and resulted in difficulty for the fine powders to aggregate and sediment to the reactor bottom. The results of the calculated fractal dimension and measured free sedimentation velocity of flocs obtained at different runs showed similar flocs properties, and indicated an easy control strategy for sedimentation of the flocs.

关键词： conical fluidized bed flocculation velocity gradient

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Self-sustained catalytic combustion of CO enhanced by micro fluidized bed: stability operation, fluidization

《环境科学与工程前沿（英文）》 2023年第17卷第9期 doi: 10.1007/s11783-023-1709-x

摘要：

● Catalytic combustion in fluidized bed realizes efficient heat and mass transfer.

关键词： Self-sustained catalytic combustion Carbon monoxide Cu_1–xCe_xO_y Fluidized bed Computational fluid dynamics

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Particle-scale simulation of fluidized bed with immersed tubes

ZHAO Yongzhi, JIANG Maoqiang, CHENG Yi

《化学科学与工程前沿（英文）》 2008年第2卷第3期页码 341-345 doi: 10.1007/s11705-008-0046-8

摘要： In order to simulate gas-solids flows with complex geometry, the boundary element method was incorporated into the implementation of a combined model of computational fluid dynamics and discrete element method. The resulting method was employed to simulate hydrodynamics in a fluidized bed with immersed tubes. The transient simulation results showed particle and bubble dynamics. The bubble coalescence and break-up behavior when passing the immersed tubes was successfully predicted. The gas-solid flow pattern in the fluidized bed is changed greatly because of the immersed tubes. As particles and gas are come in contact with the immersed tubes, the gas bubbles will be deformed. The collisions between particles and tubes will make the tubes surrounded by air pockets most of the time and this is unfavorable for the heat transfer between particles and tubes.

关键词： unfavorable computational gas-solid particle discrete

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Performance of inverse fluidized bed bioreactor in treating starch wastewater

M. RAJASIMMAN, C. KARTHIKEYAN

《化学科学与工程前沿（英文）》 2009年第3卷第3期页码 235-239 doi: 10.1007/s11705-009-0020-0

摘要： Aerobic digestion of starch industry wastewater was carried out in an inverse fluidized bed bioreactor using low-density (870 kg/m ) polypropylene particles. Experiments were carried out at different initial substrate concentrations of 2250, 4475, 6730, and 8910 mg COD/L and for various hydraulic retention times (HRT) of 40, 32, 24, 16, and 8 h. Degradation of organic matter was studied at different organic loading rates (OLR) by varying the HRT and the initial substrate concentration. From the results it was observed that the maximum COD removal of 95.6% occurred at an OLR of 1.35 kg COD/(m ·d) and the minimum of 51.8% at an OLR of 26.73 kg COD/(m ·d). The properties of biomass accumulation on the surface of particles were also studied. It was observed that constant biomass loading was achieved over the entire period of operation.

关键词： inverse fluidization low-density particles polypropylene starch biofilm